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The dioxygenase-catalysed oxidation of arenes gives, among other products, arene-cis-dihydrodiols in an enantiomerically pure form. The synthetic potential of these bio-products has been explored extensively by several research groups, including the Manchester team, resulting in successful syntheses of many important target molecules. Recently, investigators in Belfast have made the unprecedented discovery that several phenols undergo dioxygenase-catalysed conversion, in good yield, to a new cla…
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